Characterization and photooxidative behaviour of nanocomposites formed with polystyrene and LDHs organo-modified by monomer surfactant. - Institut de Chimie de Clermont-Ferrand Accéder directement au contenu
Article Dans Une Revue Polymer Année : 2005

Characterization and photooxidative behaviour of nanocomposites formed with polystyrene and LDHs organo-modified by monomer surfactant.

Résumé

Layered double hydroxide (LDH) organo-modified by a surface-active monomer, 3-sulfopropyl methacrylate (SPMA) was used as filler for polystyrene (PS). DifFerent nanocomposites SPMA/LDH:PS were prepared by bulk polymerization process using low amount of initiator. The two components, filler and polymer, as well as the degree dispersion of the reactive filler as a function of ils loading in PS were characterized by a combination of several techniques: X-ray diffraction, high resolution t3C CP-MAS NMR, 1-TIR, UV-visible, thermal analysis, SEC and MET. The nanocomposites were submitted to UV-light exposures in the presence of oxygen. The oxidation photoproducts and the rates of oxidation were compared for the varions samples. It was shown that the filler was not modifying the oxidation mechanism of the polymer, but had a slight effect on the oxidation rate.

Domaines

Matériaux
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Dates et versions

hal-00015628 , version 1 (14-02-2007)

Identifiants

  • HAL Id : hal-00015628 , version 1

Citer

Jean-Luc Gardette, Bénédicte Mailhot, Sandrine Morlat-Therias, Fabrice Leroux, Lynda Meddar. Characterization and photooxidative behaviour of nanocomposites formed with polystyrene and LDHs organo-modified by monomer surfactant.. Polymer, 2005, 46, pp.3571-3578. ⟨hal-00015628⟩
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