Enhanced photocatalytic activity of hydrozincite-TiO2 nanocomposite by copper for removal of pharmaceutical pollutant mefenamic acid in aqueous solution - Institut de Chimie de Clermont-Ferrand Accéder directement au contenu
Article Dans Une Revue Environmental Science and Pollution Research Année : 2023

Enhanced photocatalytic activity of hydrozincite-TiO2 nanocomposite by copper for removal of pharmaceutical pollutant mefenamic acid in aqueous solution

Résumé

Nanocomposites based on Hydrozincite-TiO 2 and copper-doped HZ-xCu-TiO 2 (x= 0.1; 0.25; 0.35) were synthesized in a single step using the urea method. The samples were characterized by XRD, FTIR, SEM/TEM and DRS. The study of adsorption capacity and photocatalytic efficiency of these nanocomposites have been tested on a pharmaceutical pollutant, mefenamic acid (MFA). Kinetic study of removal of MFA, indicates that this pollutant was adsorbed on the surface of the synthesized phases, according to Langmuir's model. Such adsorption proved to be well adapted in a kinetic pseudo-second order model with capacity of 13.08 mg/g for HZ-0.25Cu-TiO 2. Subsequently, the kinetics of photocatalytic degradation under UV-visible irradiation was studied according to several parameters, which allowed us to optimize our experimental conditions. The nanocomposite HZ-0.25Cu-TiO 2 showed significant removal efficiency of MFA. Elimination rate reached 100% after 20 min under UV-vis irradiation, and 77% after 7h under visible light irradiation. Repeatability tests have shown that this nanocomposite is extremely stable after six photocatalytic cycles. By-products of MFA were detected by LC/MS. These photoproducts produced by three types of reactions of hydroxylation; cyclization and cleavage of the aromatic ring. MFA underwent complete mineralization after 22 h of irradiation in the presence of the HZ-0.25Cu-TiO 2 .
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Dates et versions

hal-03843091 , version 1 (07-11-2022)

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Lekbira El Mersly, El Mountassir El Mouchtari, El Mostafa Moujahid, Samir Briche, Abdelaaziz Alaoui Tahiri, et al.. Enhanced photocatalytic activity of hydrozincite-TiO2 nanocomposite by copper for removal of pharmaceutical pollutant mefenamic acid in aqueous solution. Environmental Science and Pollution Research, 2023, 30 (9), pp.24575-24589. ⟨10.1007/s11356-022-23832-w⟩. ⟨hal-03843091⟩
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