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Article Dans Une Revue Organic Letters Année : 2021

Precise Rate Control of Pseudorotaxane Dethreading by pH-Responsive Selectively Functionalized Cyclodextrins

Résumé

A family of cyclodextrins functionalized with zero, one, two, or six amines was shown to control the rate of their threading and dethreading on a molecular axle depending on the pH and their substitution pattern. The originality of this system lies in the rate control of the switch by operating the stimulus directly on the macrocycle.

Domaines

Chimie organique
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Dates et versions

hal-03373520 , version 1 (11-10-2021)

Identifiants

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Sawsen Cherraben, Jérémy Scelle, Bernold Hasenknopf, Guillaume Vives, Matthieu Sollogoub. Precise Rate Control of Pseudorotaxane Dethreading by pH-Responsive Selectively Functionalized Cyclodextrins. Organic Letters, 2021, ⟨10.1021/acs.orglett.1c02940⟩. ⟨hal-03373520⟩
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