A non contact technique using zero-group velocity (ZGV) Lamb modes is developed to probe the bonding between two solid plates coupled by a thin layer. The layer thickness is assumed to be negligible compared with the plate thickness and the acoustic wavelength. The coupling layer is modeled by a normal and a tangential spring to take into account the normal and shear interfacial stresses. Theoretical ZGV frequencies are determined for a symmetrical bi-layer structure and the effect of the interfacial stiffnesses on the cut-off and ZGV frequencies are evaluated. Experiments are conducted with two glass plates bonded by a drop of water, oil, or salol, leading to a few micrometer thick layer. An evaluation of normal and shear stiffnesses is obtained using ZGV resonances locally excited and detected with laser ultrasonic techniques.