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Article Dans Une Revue Physical Chemistry Chemical Physics Année : 2014

Terpyridine complexes of first row transition metals and electrochemical reduction of CO₂ to CO.

Résumé

Homoleptic terpyridine complexes of first row transition metals are evaluated as catalysts for the electrocatalytic reduction of CO2. Ni and Co-based catalytic systems are shown to reduce CO2 to CO under the conditions tested. The Ni complex was found to exhibit selectivity for CO2 over proton reduction while the Co-based system generates mixtures of CO and H2 with CO : H2 ratios being tuneable through variation of the applied potential.
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Dates et versions

hal-01069154 , version 1 (31-05-2018)

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Noémie Elgrishi, Matthew B Chambers, Vincent Artero, Marc Fontecave. Terpyridine complexes of first row transition metals and electrochemical reduction of CO₂ to CO.. Physical Chemistry Chemical Physics, 2014, 16 (27), pp.13635-13644. ⟨10.1039/c4cp00451e⟩. ⟨hal-01069154⟩
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