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Article Dans Une Revue ChemCatChem Année : 2010

Catalytic Transfer of Chiral Information from an Organic Compound to a Coordination Complex

Résumé

Chirality bites: Use of a bidentate chiral sulfoxide auxiliary SO (see scheme) allows the first catalytic asymmetric synthesis of a chiral octahedral metal complex containing only achiral ligands, as shown from the conversion of the achiral complex trans-[Ru(bipyridine)2(CH3CN)2]2+ into Δ-[Ru(bipyridine)3]2+ in the presence of an excess of bipyridine.

Dates et versions

hal-01145404 , version 1 (24-04-2015)

Identifiants

Citer

Marc Fontecave. Catalytic Transfer of Chiral Information from an Organic Compound to a Coordination Complex. ChemCatChem, 2010, 2 (12), pp.1533-1534. ⟨10.1002/cctc.201000291⟩. ⟨hal-01145404⟩
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