Molecular polypyridine-based metal complexes as catalysts for the reduction of CO <sub>2</sub> - Laboratoire de Chimie des Processus Biologiques Accéder directement au contenu
Article Dans Une Revue Chemical Society Reviews Année : 2017

Molecular polypyridine-based metal complexes as catalysts for the reduction of CO 2

Résumé

Polypyridyl transition metal complexes represent one of the more thoroughly studied classes of molecular catalysts towards CO2 reduction to date. Initial reports in the 1980s began with an emphasis on 2nd and 3rd row late transition metals, but more recently the focus has shifted towards earlier metals and base metals. Polypyridyl platforms have proven quite versatile and amenable to studying various parameters that govern product distribution for CO2 reduction. However, open questions remain regarding the key mechanistic steps that govern product selectivity and efficiency. Polypyridyl complexes have also been immobilized through a variety of methods to afford active catalytic materials for CO2 reductions. While still an emerging field, materials incorporating molecular catalysts represent a promising strategy for electrochemical and photoelectrochemical devices capable of CO2 reduction. In general, this class of compounds remains the most promising for the continued development of molecular systems for CO2 reduction and an inspiration for the design of related non-polypyridyl catalysts.

Domaines

Chimie
Fichier principal
Vignette du fichier
Elgrishi_2017_Molecular.pdf (1.8 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)
Loading...

Dates et versions

hal-01446119 , version 1 (25-01-2017)

Identifiants

Citer

Noémie Elgrishi, Matthew B. Chambers, Xia Wang, Marc Fontecave. Molecular polypyridine-based metal complexes as catalysts for the reduction of CO 2. Chemical Society Reviews, 2017, ⟨10.1039/C5CS00391A⟩. ⟨hal-01446119⟩
72 Consultations
773 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More