Unveiling the mechanism of the photocatalytic reduction of CO 2 to formate promoted by porphyrinic Zr-based metal–organic frameworks - Laboratoire de Chimie des Processus Biologiques Accéder directement au contenu
Article Dans Une Revue Journal of Materials Chemistry A Année : 2022

Unveiling the mechanism of the photocatalytic reduction of CO 2 to formate promoted by porphyrinic Zr-based metal–organic frameworks

Daniel Cairnie
Pierre Mialane
Diana Iovan
Amanda Morris
Anne Dolbecq

Résumé

A complete picture of the reaction mechanism driving the photocatalytic reduction of CO 2 into formate promoted by the Zr-based porphyrinic MOF-545 in CH 3 CN/TEOA solutions is provided for the first time by combining experimental and computational approaches.

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Chimie
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Dates et versions

hal-03779922 , version 1 (11-10-2022)

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Youven Benseghir, Albert Solé-Daura, Daniel Cairnie, Amanda Robinson, Mathis Duguet, et al.. Unveiling the mechanism of the photocatalytic reduction of CO 2 to formate promoted by porphyrinic Zr-based metal–organic frameworks. Journal of Materials Chemistry A, 2022, 10 (35), pp.18103-18115. ⟨10.1039/d2ta04164b⟩. ⟨hal-03779922⟩
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