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Article Dans Une Revue Chemical Communications Année : 2015

Versatile functionalization of carbon electrodes with a polypyridine ligand: metallation and electrocatalytic H + and CO 2 reduction

Résumé

A strategy is proposed for immobilization of homogeneous catalysts whereby a glassy carbon electrode is functionalized by electro-grafting of a ligand, terpyridine. The modified electrode can easily be metallated with cobalt and shows activity towards catalytic proton and CO2 reduction. The metal can be removed and the electrode re-metallated at will.

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Chimie
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Dates et versions

hal-03919435 , version 1 (02-01-2023)

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Noémie Elgrishi, Sophie Griveau, Matthew Chambers, Fethi Bedioui, Marc Fontecave. Versatile functionalization of carbon electrodes with a polypyridine ligand: metallation and electrocatalytic H + and CO 2 reduction. Chemical Communications, 2015, 51 (14), pp.2995-2998. ⟨10.1039/c4cc10027a⟩. ⟨hal-03919435⟩
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