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Article Dans Une Revue Journal of Chemical Physics Année : 1991

Spectroscopy, dynamics, and chaos of the CS2 molecule: Fourier transform and phase-space analysis

Résumé

In this paper we analyze the vibrational spectra of the Σ+g ground state of CS2, the experimental results of which have been described in a forth coming paper. We show that, up to 12 000 cm-1, CS2 can be described by a system of two degrees of freedom strongly coupled by a 1:2 type Fermi resonance. The corresponding vibrational spectra are refitted with the aid of only seven parameters. Analysis of the spectra by the statistical Fourier transform technique reveals stroboscopic effects between the symmetric stretching mode and the bending mode. The distinction between the ``stroboscopic hole'' due to these effects and the ``correlation hole'' due to nonintegrable terms in the Hamiltonian is discussed in detail. The study of the topology of the phase space of CS2 in the regular and chaotic cases is carried out in the basis described by a vibrational angular momentum which includes the Fermi resonance. We show the analogy between the localization of the wave packets of the eigenstates and the trajectories. We also show the destabilization of the trajectories due to a term in the Hamiltonian which couples neighboring polyads and which is a second Fermi resonance. We show that only two resonances are enough to induce a chaotic situation.
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Dates et versions

hal-01118159 , version 1 (18-02-2015)

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J. P. Pique, M. Joyeux, J. Manners, G. Sitja. Spectroscopy, dynamics, and chaos of the CS2 molecule: Fourier transform and phase-space analysis. Journal of Chemical Physics, 1991, 95 (12), pp.8744-8752. ⟨10.1063/1.461210⟩. ⟨hal-01118159⟩
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