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Article Dans Une Revue ChemPhysChem Année : 2011

Alternating current measurements in scanning electrochemical microscopy, part 2: detection of adsorbates.

Résumé

A scanning electrochemical microscope (SECM) in ac mode is used for the characterisation of the adsorption process during the hydrogen evolution reaction (HER) in sulfuric acid solution. It is shown that this technique allows quantitative analysis of the adsorption process, and measurements of the differential capacitance with the frequency as parameter are obtained. The time constant for relaxation of adsorbed hydrogen (H(ads)) is approximately 2 Hz, and analysis of the Nyquist plot allows direct evaluation of the charge involved. In addition, the direct comparison of the usual electrochemical impedance data and ac-SECM results obtained simultaneously permits characterisation of processes occurring at the surface and in solution.

Dates et versions

hal-00816609 , version 1 (22-04-2013)

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Dao Trinh, Michel Keddam, Xosé Ramon Novoa, Vincent Vivier. Alternating current measurements in scanning electrochemical microscopy, part 2: detection of adsorbates.. ChemPhysChem, 2011, 12 (11), pp.2177-2183. ⟨10.1002/cphc.201001085⟩. ⟨hal-00816609⟩
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