Programmable Logic Controllers (PLCs) are industrial digital computers used as automation controllers in manufacturing processes. The Ladder language is a programming language used to develop PLC software. Our aim is to prove that a given Ladder program conforms to an expected temporal behaviour given as a timing chart, describing scenarios of execution. We translate the Ladder code and the timing chart into a program for the Why3 environment, within which the verification proceeds by generating verification conditions, to be checked valid using automated theorem provers. The ultimate goal is twofold: first, by obtaining a complete proof, we can verify the conformance of the Ladder code with respect to the timing chart with a high degree of confidence. Second, when the proof is not fully completed, we obtain a counterexample, illustrating a possible execution scenario of the Ladder code which does not conform to the timing chart.