Design of experiments as tools to tailor impregnated polymers specific for radionuclides separation in microsystems - Laboratoire Physico-Chimie Curie [Institut Curie] Accéder directement au contenu
Article Dans Une Revue Reactive and Functional Polymers Année : 2018

Design of experiments as tools to tailor impregnated polymers specific for radionuclides separation in microsystems

Résumé

An experimental design is described for optimization of the microscopic morphology of a methacrylate monolith that was elaborated for chromatographic separation of radionuclides in nitric acid media. This paper presents a systematic study of the synthesis of the polymeric porous monolith poly(ethylene glycol dimethacrylate-co-allyl methacrylate) used as solid-phase support and a post-functionalization of the monolith in microsystem with tributyl phosphate extractant. Polymerization time and chemical composition of the polymerizable mixture that comprises water, 1,4-butanediol, 1-propanol, monomers were chosen as the most relevant experimental factors of the photochemical process. Using the globules area as a significant response of an experimental design, the monolith morphology can be predicted. A new versatile and robust impregnation process was developed in microsystem. The designed micro chromatographic system showed a good resistance in concentrated nitric acid and a great loading capacity compared to commercially available solution (150 mg U versus 75 mgU/g resin).
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Dates et versions

hal-04030853 , version 1 (15-03-2023)

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Marion Losno, Ivan Ferrante, René Brennetot, Stéphanie Descroix, Clarisse Mariet. Design of experiments as tools to tailor impregnated polymers specific for radionuclides separation in microsystems. Reactive and Functional Polymers, 2018, 127, pp.48-54. ⟨10.1016/j.reactfunctpolym.2018.04.001⟩. ⟨hal-04030853⟩
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