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Article Dans Une Revue Chemistry of Materials Année : 2007

Composition and size-dependent extinction coefficient of colloidal PbSe quantum dots

Résumé

Inductively coupled plasma mass spectrometry (ICP-MS) was combined with UV–vis−NIR spectrophotometry and transmission electron microscopy to determine the nanocrystal composition and molar extinction coefficient ϵ of colloidal PbSe quantum dot (Q-PbSe) suspensions. The ICP-MS results show a nonstoichiometric Pb/Se ratio, with a systematic excess of lead for all samples studied. The observed ratio is consistent with a faceted spherical Q-PbSe model, composed of a quasi stoichiometric Q-PbSe core terminated by a Pb surface shell. At high photon energies, we find that ϵ scales with the nanocrystal volume, irrespective of the Q-PbSe size. From ϵ, we calculated a size-independent absorption coefficient. Its value is in good agreement with the theoretical value for bulk PbSe. At the band gap, ϵ is size-dependent. The resulting absorption coefficient increases quadratically with decreasing Q-PbSe size. Calculations of the oscillator strength of the first optical transition are in good agreement with theoretical tight binding calculations, showing that the oscillator strength increases linearly with Q-PbSe size.

Dates et versions

hal-00283128 , version 1 (29-05-2008)

Identifiants

Citer

Iwan Moreels, Karel Lambert, David de Muynck, Frank Vanhaecke, Dirk Poelman, et al.. Composition and size-dependent extinction coefficient of colloidal PbSe quantum dots. Chemistry of Materials, 2007, 19, pp.6101-6106. ⟨10.1021/cm071410q⟩. ⟨hal-00283128⟩
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