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Article Dans Une Revue Phosphorus, Sulfur, and Silicon and the Related Elements Année : 2007

Synthesis and characterization of diaminodithio- and aminotrithiophosphoric acid esters

Résumé

The synthesis and characterization of a series of five new diaminodithiophosphoric acid esters ((RRN)-R-1-N-2)(2)P(S) SR and five new aminotrithiophosphoric acid esters ((RRN)-R-1-N-2)P(S)(SR)(2) are described. The structure of two of these compounds, the diaminodithio derivative (iPr(2)N)(2)P(S)SCH2Ph and the aminotrithio derivative (iPr(2)N)P(S)(SCH2Ph)(2) , has been determined by single crystal X-ray diffraction. These series of compounds are potentially usable as agents for reversible addition-fragmentation chain transfer polymerization.
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Dates et versions

hal-00283227 , version 1 (29-05-2008)

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Patrice Marchand, Anca Meffre, Bruno Donnadieu, Daniel Taton, Yves Gnanou, et al.. Synthesis and characterization of diaminodithio- and aminotrithiophosphoric acid esters. Phosphorus, Sulfur, and Silicon and the Related Elements, 2007, 182 (6), pp.1233-1244. ⟨10.1080/10426500601160694⟩. ⟨hal-00283227⟩
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