Oxaphospholene and oxaphosphinene heterocycles via RCM using unsymmetrical phosphonates or functional phosphinates - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Tetrahedron Année : 2009

Oxaphospholene and oxaphosphinene heterocycles via RCM using unsymmetrical phosphonates or functional phosphinates

Résumé

New phosphorus heterocycles were synthesized using RCM reaction. They were prepared from unsymmetrical or polyfunctional insaturated precursor in 50 to 87% yields solving the problem of possible competitive side reactions. In parallel hydroxyphosphinate scaffolds represent a versatile starting material and could be of great interest for the synthesis of phosphosugar libraries.

Domaines

Chimie organique

Dates et versions

hal-00537606 , version 1 (18-11-2010)

Identifiants

Citer

Pierre Fourgeaud, Camille Midrier, Jean-Pierre Vors, Jean-Noël Volle, Jean-Luc Pirat, et al.. Oxaphospholene and oxaphosphinene heterocycles via RCM using unsymmetrical phosphonates or functional phosphinates. Tetrahedron, 2009, 66, pp.758-764. ⟨10.1016/j.tet.2009.11.049⟩. ⟨hal-00537606⟩
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