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Article Dans Une Revue Journal of Physics: Condensed Matter Année : 2009

Establishing the structure of GeS2 at high pressures and temperatures: a combined approach using x-ray and neutron diffraction

Résumé

The change in structure of glassy GeS2 with pressure increasing to 5 GPa at ambient temperature was explored by using in situ neutron and x-ray diffraction. Under ambient conditions, the glass structure is made from a mixture of corner- and edge-sharing Ge(S1/2)4 tetrahedra where 47(5)% of the Ge atoms are involved in edge-sharing configurations. The network formed by these tetrahedra orders on an intermediate range as manifested by the appearance of a pronounced first sharp diffraction peak in the measured total structure factors at a scattering vector k = 1.02(2) °A −1 which has a large contribution from Ge–Ge correlations. The intermediate range order breaks down when the pressure on the glass increases above ≈2 GPa but there does not appear to be a significant alteration of the Ge–S coordination number or corresponding bond length with increasing density. The results for the glass are consistent with a densification mechanism in which there is a replacement of edge-sharing by corner-sharing Ge centred tetrahedral motifs and/or a reduction in the Ge–ˆS–Ge bond angle between corner-sharing tetrahedral motifs with increasing pressure. The change in structure with increasing temperature at a pressure of 5 GPa was also investigated by means of in situ x-ray diffraction as the glass crystallized and then liquefied. At 5.2(1) GPa and 828(50) K the system forms a tetragonal crystal, with space group I ¯42d and cell parameters a = b = 4.97704(12) and c = 9.5355(4) A° , wherein corner-sharing Ge(S1/2)4 tetrahedra pack to form a dense three-dimensional network. A method is described for correcting x-ray diffraction data taken in situ under high pressure, high temperature conditions for a cylindrical sample, container and gasket geometry with a parallel incident beam and with a scattered beam that is defined using an oscillating radial collimator. A method is also outlined for obtaining coordination numbers from direct integration of the peaks in measured x-ray total pair distribution functions

Dates et versions

hal-00545224 , version 1 (09-12-2010)

Identifiants

Citer

Anita Zeidler, Jameswe Drewitt, Philip S Salmon, Adrian C Barnes, Wilson a Crichton, et al.. Establishing the structure of GeS2 at high pressures and temperatures: a combined approach using x-ray and neutron diffraction. Journal of Physics: Condensed Matter, 2009, 21, pp.474217. ⟨10.1088/0953-8984/21/47/474217⟩. ⟨hal-00545224⟩
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