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Article Dans Une Revue Chemistry - A European Journal Année : 2012

One-electron oxidized copper(II) salophen complexes: phenoxyl versus diiminobenzene radical species

Résumé

Where is the radical? The π-system of the diiminobenzene bridge adds a putative oxidation site to prophenoxyl copper(II) salophen complexes. It is shown that the bridge is effectively redox active and that the radical site (phenoxyl vs. diiminobenzene bridge) in the above cations is tuned by selective methoxy substitution (see figure).

Dates et versions

hal-00660915 , version 1 (18-01-2012)

Identifiants

Citer

A. Kochem, O. Jarjayes, B. Baptiste, C. Philouze, H. Vezin, et al.. One-electron oxidized copper(II) salophen complexes: phenoxyl versus diiminobenzene radical species. Chemistry - A European Journal, 2012, 18, pp.1068 - 1072. ⟨10.1002/chem.201102882⟩. ⟨hal-00660915⟩
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