Structure-Property Relationships in Tricyanoferrate(III) Building Blocks and Trinuclear Cyanide-Bridged Complexes - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue European Journal of Inorganic Chemistry Année : 2016

Structure-Property Relationships in Tricyanoferrate(III) Building Blocks and Trinuclear Cyanide-Bridged Complexes

Résumé

The preparation, structures, and magnetic properties of two tricyanoferrates, [NEt4]2[(Tp*Me)FeII(CN)3]·MeCN (1) and [NEt4][(Tp*Me)FeIII(CN)3]·H2O (2), and three trinuclear derivatives, {[(Tp*Me)FeIII(CN)3]2[NiII(L)2]}·n(solvent) (L = bpy, 3; tren, 4; DETA,5) are described. Magnetic measurements show that 2 is an S = 1/2 complex [g = 2.65(1)], while 3–5 display ST = 2 spin ground states, owing to cyanide-mediated ferromagnetic exchange between FeIII LS (S = 1/2) and NiII (S = 1) ions....

Dates et versions

hal-01340250 , version 1 (30-06-2016)

Identifiants

Citer

Yuanzhu Zhang, Uma P. Malik, Benjamin Quiggins, Hung Nguyen, Christopher C. Beedle, et al.. Structure-Property Relationships in Tricyanoferrate(III) Building Blocks and Trinuclear Cyanide-Bridged Complexes. European Journal of Inorganic Chemistry, 2016, pp. 2432-2442. ⟨10.1002/ejic.201600199⟩. ⟨hal-01340250⟩

Collections

CNRS INC-CNRS
32 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More