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Article Dans Une Revue Catalysis Communications Année : 2016

Monolithic acidic catalysts for the dehydration of xylose into furfural

Résumé

We report the application of hierarchically porous zirconium phosphate monoliths with high surface area as acidic heterogeneous catalysts for the dehydration of xylose into furfural. Analyses by NH3-temperature programmed desorption and 31P solid state NMR reveal the presence of both Lewis and Brønsted acid sites in the as-synthesized zirconium phosphate monolith and that calcined at 600 °C. High accessibility and availability of the acidic sites and easy separation of the monolith from the liquid medium result in good catalytic activity (initial reaction rate for furfural production as 8.7 mmol gcat−1 h−1) with easy handling of the catalyst

Domaines

Chimie

Dates et versions

hal-01369195 , version 1 (20-09-2016)

Identifiants

Citer

Yang Zhu, Kanamori Kazuyoshi, Nicolas Brun, Carl-Hugo Pelisson, Nirmalya Moitra, et al.. Monolithic acidic catalysts for the dehydration of xylose into furfural. Catalysis Communications, 2016, 87, pp.112-115. ⟨10.1016/j.catcom.2016.09.014⟩. ⟨hal-01369195⟩
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