Theoretical Analysis of Critical Flowable Physical Gel Cross-Linked by Metal Ions and Polyacrylamide-Derivative Associating Polymers Containing Imidazole Groups - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Polymers Année : 2017

Theoretical Analysis of Critical Flowable Physical Gel Cross-Linked by Metal Ions and Polyacrylamide-Derivative Associating Polymers Containing Imidazole Groups

Résumé

When the polymer chains are cross-linked by physical bonds having a finite lifetime, the relaxation time and viscosity do not diverge at the gel point though percolation occurs. These undivergent quantities are related to the finite-sized "largest relaxed cluster," which can relax before it breaks. Its size is the key rheological parameter characterizing of the critical physical gels. In order to evaluate this characteristic size, we propose here a generalized phenomenological model for the viscoelasticity of critical physical gels. We apply the theory to the previously reported experimental result for the physical gel consisting of polyacrylamide-derivative associating polymers containing imidazole groups cross-linked by coordination bonds with Ni ions. We successfully estimate the size of the largest relaxed cluster and the fractal dimension. The size is in good agreement with that estimated from the mean-square displacement of probe particles at the gel point by microrheological measurement. We also compare this system with the poly(vinyl alcohol) hydrogel cross-linked by borate ions, and show that the difference in the cluster structures is originating from the differences of precursor chain properties such as overlap concentration and radius of gyration and of the cross-linking states in these systems.

Dates et versions

hal-01584154 , version 1 (08-09-2017)

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Hiroto Ozaki, Tetsuharu Narita, Tsuyoshi Koga, Tsutomu Indei. Theoretical Analysis of Critical Flowable Physical Gel Cross-Linked by Metal Ions and Polyacrylamide-Derivative Associating Polymers Containing Imidazole Groups. Polymers, 2017, 9 (7), pp.256. ⟨10.3390/polym9070256⟩. ⟨hal-01584154⟩
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