Alkali and alkaline earth metal ion binding by a foldamer capsule: selective recognition of magnesium hydrate
Résumé
Alkali and alkaline earth metal ion binding by an aromatic oligoamide foldamer was shown to induce its folding into a helical capsule. CD and NMR titrations revealed tight and selective binding of Mg 2+. Crystallographic studies demonstrated that, depending on the metal, binding may involve the first or second coordination spheres of the metal hydrates.
Domaines
Chimie de coordination
Origine : Fichiers produits par l'(les) auteur(s)
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