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Article Dans Une Revue Journal of Polymer Science Part A: Polymer Chemistry Année : 2011

Synthesis of poly(oxyethylene phosphate)-g-poly(ethylene oxide) via the “grafting onto” approach by “click” chemistry

Résumé

A general method for the synthesis of grafted poly(alkylene phosphate)s is presented by combination of Atherton–Todd reaction and “click” chemistry. In the first step, the proposed method uses in a first step the Atherton-–Todd reaction to yield poly(tetraoxyethylene phosphate) with pendant acetylenic groups from poly(tetraoxyethylene H-phosphonate). In a the second step, “click” functionalization of the acetylene-containing poly(tetraoxyethylene phosphate) with azido-terminated poly(ethylene oxide)PEO leads to poly(tetraoxyethylene phosphate)-g-poly(ethylene oxide).

Dates et versions

hal-01905426 , version 1 (25-10-2018)

Identifiants

Citer

Karima Oussadi, V. Montembault, Laurent Fontaine. Synthesis of poly(oxyethylene phosphate)-g-poly(ethylene oxide) via the “grafting onto” approach by “click” chemistry. Journal of Polymer Science Part A: Polymer Chemistry, 2011, 49 (23), pp.5124 - 5128. ⟨10.1002/pola.24950⟩. ⟨hal-01905426⟩
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