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Article Dans Une Revue Organic Letters Année : 2018

Xanthate-Mediated Incorporation of Quaternary Centers into Heteroarenes

Résumé

The xanthate-mediated addition of tertiary alkyl radicals to heteroarenes enabled the easy functionalization of heteroaromatic rings as well as more decorated structures, such as marketed drugs or agrochemicals. This work provides a synthetic tool for efficiently exploring the chemical space by allowing late-stage diversification with a high tolerance toward functional groups.

Domaines

Chimie organique
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Dates et versions

hal-02094367 , version 1 (09-04-2019)

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Copyright (Tous droits réservés)

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Vincent Revil-Baudard, Jean-Pierre Vors, Samir Z. Zard. Xanthate-Mediated Incorporation of Quaternary Centers into Heteroarenes. Organic Letters, 2018, 20 (12), pp.3531-3535. ⟨10.1021/acs.orglett.8b01299⟩. ⟨hal-02094367⟩
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