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Article Dans Une Revue Chemical Communications Année : 2018

A luminescent [Pd4Ru8](24+) supramolecular cage

Résumé

A phosphorescent cage of the form [Pd4Ru8](24+) is reported. The cage was formed using the metalloligand [Ru(dtbubpy)(2)(qpy)](2+), where qpy = 4,4': 2',2 `': 4 `',4'''-quaterpyridine and dtbubpy = 4,4'-di-tert-butyl-2,2'-bipyridine. The cage has been characterised by NMR, ESI-MS, TEM and X-ray diffraction analyses and its emission properties elucidated by steady-state and time-resolved emission spectroscopy.

Domaines

Chimie

Dates et versions

hal-02140946 , version 1 (27-05-2019)

Identifiants

Citer

Diego Rota Martir, David B. Cordes, Alexandra M. Z. Slawin, Daniel Escudero, Denis Jacquemin, et al.. A luminescent [Pd4Ru8](24+) supramolecular cage. Chemical Communications, 2018, 54 (47), pp.6016-6019. ⟨10.1039/c8cc02104j⟩. ⟨hal-02140946⟩
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