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Article Dans Une Revue European Journal of Inorganic Chemistry Année : 2008

Chiral Diphosphite‐Modified Rhodium(0) Nanoparticles: Catalyst Reservoir for Styrene Hydroformylation

Résumé

The organometallic synthesis of rhodium nanoparticles stabilized with diphosphite ligands is described. These nanoparticles were investigated as catalysts in the styrene hydroformylation reaction, and their activity and selectivity were compared with those of similar molecular complexes. NMR spectroscopic studies performed during the course of the catalytic reaction showed that the synthesized nanoparticles are not stable and produce molecular species.

Dates et versions

hal-02350961 , version 1 (06-11-2019)

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Citer

M. Rosa Axet, Sergio Castillon, Carmen Claver, Karine Philippot, Pierre Lecante, et al.. Chiral Diphosphite‐Modified Rhodium(0) Nanoparticles: Catalyst Reservoir for Styrene Hydroformylation. European Journal of Inorganic Chemistry, 2008, 2008 (22), pp.3460-3466. ⟨10.1002/ejic.200800421⟩. ⟨hal-02350961⟩
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