Encoding Chiral Molecular Information in Metal Structures - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Chemistry - A European Journal Année : 2020

Encoding Chiral Molecular Information in Metal Structures

Résumé

The concept of encoding molecular information in bulk metals has been proposed over the past decade. The structure of various types of molecules, including enantiomers, can be imprinted in achiral substrates. Typically, to encode metals with chiral information, several approaches, based on chemical and electrochemical concepts, can be used. In this Minireview, recent achievements with respect to the development of such materials are discussed, including the entrapment of chiral biomolecules in metals, the chiral imprinting of metals, as well as the combination of imprinting with nanostructuring. The features and potential applications of these designer materials, such as chirooptical properties, enantioselective adsorption and separation, as well as their use for asymmetric synthesis will be presented. This will illustrate that the development of molecularly encoded metal structures opens up very interesting perspectives, especially in the frame of chiral technologies.
Fichier principal
Vignette du fichier
Unformatted version.pdf (1.02 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)
Loading...

Dates et versions

hal-02510336 , version 1 (17-03-2020)

Identifiants

Citer

Chularat Wattanakit, Alexander Kuhn. Encoding Chiral Molecular Information in Metal Structures. Chemistry - A European Journal, 2020, 26 (14), pp.2993-3003. ⟨10.1002/chem.201904835⟩. ⟨hal-02510336⟩
126 Consultations
270 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More