Critical Role of the Coordination Environment of Palladium Dichloride on the Course of Its Reaction with Secondary Benzylic Alcohols: Selective Oxidation or Etherification Catalysts - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Organometallics Année : 2000

Critical Role of the Coordination Environment of Palladium Dichloride on the Course of Its Reaction with Secondary Benzylic Alcohols: Selective Oxidation or Etherification Catalysts

Résumé

In refluxing 1,2-dichloroethane under an argon atmosphere, 1-indanol led to a high yield of 1-indanone in the presence of sodium carbonate and catalytic amounts of (R4N)2PdCl4, while the use of PdCl2(RCN)2 as catalyst afforded di(1-indanyl) oxide quantitatively. These distinct reactive pathways would be due to the different electronic properties of the catalysts. The etherification reaction is limited to primary and secondary benzylic alcohols.

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Chimie

Dates et versions

hal-02540866 , version 1 (12-04-2020)

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Citer

Sandrine Bouquillon, Françoise Hénin, Jacques Muzart. Critical Role of the Coordination Environment of Palladium Dichloride on the Course of Its Reaction with Secondary Benzylic Alcohols: Selective Oxidation or Etherification Catalysts. Organometallics, 2000, 19 (7), pp.1434-1437. ⟨10.1021/om990961q⟩. ⟨hal-02540866⟩

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