Catalytic reductive deoxygenation of esters to ethers driven by a hydrosilane activation through non-covalent interactions with a fluorinated borate salt - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Catalysis science and Technology Année : 2020

Catalytic reductive deoxygenation of esters to ethers driven by a hydrosilane activation through non-covalent interactions with a fluorinated borate salt

Résumé

We report a catalytic and transition metal-free reductive deoxygenation of esters to ethers through the use of a hydrosilane and a fluorinated borate BArF salt as catalyst. Experimental and theoretical studies support the role of noncovalent interactions between the fluorinated catalyst, the hydrosilane and the ester substrate in the reaction mechanism.
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hal-02903307 , version 1 (20-07-2020)

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Vincent Rysak, Ruchi Dixit, Xavier Trivelli, Nicolas Merle, Francine Agbossou Niedercorn, et al.. Catalytic reductive deoxygenation of esters to ethers driven by a hydrosilane activation through non-covalent interactions with a fluorinated borate salt. Catalysis science and Technology, 2020, 10 (14), pp.4586-4592. ⟨10.1039/D0CY00775G⟩. ⟨hal-02903307⟩
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