Interception of a Rh(I)–Rh(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)2{(R,R)-Ph–BPE}] - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Dalton Transactions Année : 2012

Interception of a Rh(I)–Rh(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)2{(R,R)-Ph–BPE}]

Résumé

Reaction of [Rh(CO)2{(R,R)-Ph–BPE}][BF4] 1 under 7 bar H2 provides the dihydride [Rh(H)2(CO)2{(R,R)-Ph–BPE}] [BF4] 3, which reacts with the neutral hydride [Rh(H)(CO) {(R,R)-Ph–BPE}] 2 arising from 3 in THF. The resulting complex is the dimeric monocationic Rh(I)–Rh(III) complex [Rh(H)2(CO)2{(R,R)-Ph–BPE}][BF4] 4.
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Dates et versions

hal-02909585 , version 1 (30-07-2020)

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Delphine Crozet, David Mckay, Christian Bijani, Aitor Gual, Cyril Godard, et al.. Interception of a Rh(I)–Rh(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)2{(R,R)-Ph–BPE}]. Dalton Transactions, 2012, 41 (12), pp.3369. ⟨10.1039/c2dt12400a⟩. ⟨hal-02909585⟩
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