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Article Dans Une Revue Journal of the American Chemical Society Année : 2020

Absolute Templating of M(111) Cluster Surrogates by Galvanic Exchange

Résumé

The precise preparation of monodisperse nanomaterials is among the most fundamental tasks in inorganic synthesis and materials science. Achieving this goal by galvanic exchange is hardly predictable and often results in major structural changes and polydisperse mixtures. Taking advantage of the enhanced stability imparted by ambiphilic carbenes, we report and rationalize the absolute templating, the complete exchange of metals in a template, of group 11 clusters across the entire coinage metal family by means of galvanic exchange. We further delineate that these species provide a molecular model for better understanding the reduction of CO 2 at M(111) coinage metal surfaces.
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Dates et versions

hal-03001149 , version 1 (12-11-2020)

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  • HAL Id : hal-03001149 , version 1

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Jesse L Peltier, Michele Soleilhavoup, David Martin, Rodolphe Jazzar, Guy Bertrand. Absolute Templating of M(111) Cluster Surrogates by Galvanic Exchange. Journal of the American Chemical Society, 2020. ⟨hal-03001149⟩
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