Tuning the functional properties of lignocellulosic films by controlling the molecular and supramolecular structure of lignin - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue International Journal of Biological Macromolecules Année : 2021

Tuning the functional properties of lignocellulosic films by controlling the molecular and supramolecular structure of lignin

Résumé

This study investigated the relationships between lignin molecular and supramolecular structures and their functional properties within cellulose-based solid matrix, used as a model biodegradable polymer carrier. Two types of derivatives corresponding to distinct structuration levels were prepared from a single technical lignin sample (PB1000): phenol-enriched oligomer fractions and colloidal nanoparticles (CLP). The raw lignin and its derivatives were formulated with cellulose nanocrystals or nanofibrils to prepare films by chemical oxidation or pressure-assisted filtration. The films were tested for their water and lignin retention capacities, radical scavenging capacity (RSC) and antimicrobial properties. A structural investigation was performed by infrared, electron paramagnetic resonance spectroscopy and microscopy. The composite morphology and performance were controlled by both the composition and structuration level of lignin. Phenol-enriched oligomers were the compounds most likely to interact with cellulose, leading to the smoothest film surface. Their RSC in film was 4-to 6-fold higher than that of the other samples. The organization in CLP led to the lowest RSC but showed capacity to trap and stabilize phenoxy radicals. All films were effective against S. aureus (gram negative) whatever the lignin structure. The results show the possibility to tune the performances of these composites by exploiting lignin multi-scale structure.
Fichier principal
Vignette du fichier
Gerbin et al 2021.pdf (2.36 Mo) Télécharger le fichier
Origine : Publication financée par une institution

Dates et versions

hal-03211599 , version 1 (28-04-2021)

Licence

Paternité - Pas d'utilisation commerciale - Pas de modification

Identifiants

Citer

Elise Gerbin, G N Rivière, Laurence Foulon, Yves-Michel M Frapart, Betty Cottyn, et al.. Tuning the functional properties of lignocellulosic films by controlling the molecular and supramolecular structure of lignin. International Journal of Biological Macromolecules, 2021, 181, pp.136 - 149. ⟨10.1016/j.ijbiomac.2021.03.081⟩. ⟨hal-03211599⟩
233 Consultations
77 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More