Rhodium-Catalyzed Enantioselective Synthesis of Highly Fluorescent and CPL-Active Dispiroindeno[2,1-c]fluorenes
Résumé
The enantioselective synthesis of chiral [7]-helical dispirodihydro[2,1-c]indenofluorenes (DSF-IFs) was achieved for the first time in good yields with high er values (er up to 99 : 1). The crucial step of the whole reaction sequence was the enantioselective intramolecular [2+2+2] cycloaddition of tethered triynediols to indenofluorenediols, which was catalyzed by a Rh/SEGPHOS (R) complex. Further transformations led to the corresponding DSF-IFs. The prepared helically chiral DSF-IFs combine circularly polarized luminescence (CPL) activity (g(lum)=similar to 10(-3)) with exceptionally high fluorescence quantum yields (up to phi(lum)=0.97).
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Kotora et al-2021-Rhodium Catalyzed Enantioselective Synthesis of Highly Fluorescent and CPL.pdf (1.17 Mo)
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kotora_chem202100759-sup-0001-misc_information.pdf (3.64 Mo)
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