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Article Dans Une Revue Reaction Chemistry & Engineering Année : 2021

Hydroamination of ethylene with NH 3 induced by non-thermal atmospheric plasma

Résumé

We show here that non-thermal atmospheric plasma induces the cleavage of the N–H bond of NH 3 to form aminium radicals, which then add onto ethylene to form ethylamine in 17% yield. This technology can be also extended to n-octene, leading to the formation of 1-octylamine, i.e. with anti-Markovnikov addition of NH3.

Domaines

Catalyse
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Dates et versions

hal-03421008 , version 1 (09-11-2021)

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Julien Dieu, François Jérôme, Catherine Batiot-Dupeyrat. Hydroamination of ethylene with NH 3 induced by non-thermal atmospheric plasma. Reaction Chemistry & Engineering, 2021, ⟨10.1039/D1RE00407G⟩. ⟨hal-03421008⟩
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