%0 Journal Article %T Growth and characterisation of single grain Al-Cu-Ru icosahedral quasicrystals from self-fluxes %+ Hokkaido University [Sapporo, Japan] %+ Tohoku University [Sendai] %+ Science et Ingénierie des Matériaux et Procédés (SIMaP) %+ Laboratoire de cristallographie et sciences des matériaux (CRISMAT) %+ Synchrotron SOLEIL (SSOLEIL) %A Toyonaga, Kotoba %A Shibata, Ryosei %A Yamada, Tsunetomo %A de Boissieu, Marc %A Peréz, Olivier %A Fertey, Pierre %A Takakura, Hiroyuki %< avec comité de lecture %@ 1478-6435 %J Philosophical Magazine %I Taylor & Francis %V 100 %N 17 %P 2220-2243 %8 2020-09-01 %D 2020 %R 10.1080/14786435.2020.1762015 %K Solution growth %K Quasicrystals %K X-ray diffraction %Z Physics [physics]/Condensed Matter [cond-mat]Journal articles %X In order to obtain high-quality single grains of the Al-Cu-Ru icosahedral quasicrystal (iQC), suitable for a structure analysis, the crystal growth conditions with the self-flux method have been studied. The melts of the master alloys with the compositions of Al57.0+xCu39.5-xRu3.5 (x = 0, 2.5, 5, 7.5, 10) and Al62.0Cu34.0+y Ru4.0-y (y = 0, 0.5, 1.5) were held at 1150°C for 2 h, then cooled down to 800, 900, or 1000°C at a rate of −2 K/h, and subsequently retained for various durations, up to 750 h. Single grain iQCs having several millimetre-sizes, which were evaluated their quality by powder X-ray diffraction (XRD), were grown throughout this study. The peak of (664004) reflection in powder XRD of the iQCs grown at 1000°C has approximately 50% narrower width than that grown at 800°C. The inhomogeneity of the compositions intra- as well as inter-grains grown at 800°C was observed. High-quality single grains with homogeneous composition could be achieved with a long-time annealing at 900°C or regardless of the annealing time at 1000°C. By changing the Al/Cu ratio of the master alloys, the composition could also be controlled for the iQCs grown at 1000°C. Single-crystal XRD experiment with synchrotron radiation on Al66.6Cu16.4Ru17.0 iQC, grown at 1000°C, resulted in the collection of 2680 independent Bragg reflections that confirms the high-quality of the sample. The phase retrieval of the diffraction data resulted successfully in obtaining the structure solution, which reveals some characteristic features of this face-centred iQC structure. %G English %L hal-03443270 %U https://cnrs.hal.science/hal-03443270 %~ CEA %~ UGA %~ CNRS %~ INSA-ROUEN %~ INPG %~ SIMAP %~ COMUE-NORMANDIE %~ DSV %~ INC-CNRS %~ UNIV-PARIS-SACLAY %~ SYNCHROTRON-SOLEIL %~ CEA-DRF %~ UNIROUEN %~ ENSICAEN %~ UNICAEN %~ CRISMAT %~ INSA-GROUPE %~ TEST-HALCNRS %~ UGA-EPE %~ GS-PHYSIQUE %~ INSTITUT-SCIENCES-LUMIERE %~ TEST2-HALCNRS %~ TEST3-HALCNRS