Electrochemical, vibrational, optical and Hirshfeld surface studies of 3D- bis[di(1,10-phenanthrolinium) (1,10-phenanthroline)] hexacyanoferrate ethanol trihydrate - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Journal of Molecular Structure Année : 2022

Electrochemical, vibrational, optical and Hirshfeld surface studies of 3D- bis[di(1,10-phenanthrolinium) (1,10-phenanthroline)] hexacyanoferrate ethanol trihydrate

Résumé

In this work, structure, spectroscopic, optical and electrochemical investigation of a new complex of the hexacyanoferrate [Fe(CN)(6)](4-) and 1,10-phenanthroline have been examined. The complex has been resolved by single crystal X-ray diffraction at room temperature. In the crystal structure individual complex is interconnected through strong hydrogen bonds of type O-H...N, N-H...O and pi-pi interactions to obtain a 3D supramolecular shape. The three-dimensional Hirshfeld surface (3D-HS) investigation and the two-dimensional unique finger impression plots (2D-FP) reveal that the H... O, H... N and H... H contacts dominates the structure. The cyclic voltammetry explores the electrochemical performance of the complex. The complex reveals excellent supercapacitives properties with a higher specific capacitance equal to 1000 F.g(-1) for the scans rate 10 mVs(-1).

Domaines

Matériaux
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Dates et versions

hal-03631697 , version 1 (05-04-2022)

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Wafa Selmi, Nabil Hosni, Mathieu Marchivie, J. Ben Naceur, Hager Maghraoui-Meherzi, et al.. Electrochemical, vibrational, optical and Hirshfeld surface studies of 3D- bis[di(1,10-phenanthrolinium) (1,10-phenanthroline)] hexacyanoferrate ethanol trihydrate. Journal of Molecular Structure, 2022, 1254, 132320 (8 p.). ⟨10.1016/j.molstruc.2021.132320⟩. ⟨hal-03631697⟩
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