Poly(vinylidene fluoride)-Stabilized Black γ-Phase CsPbI3Perovskite for High-Performance Piezoelectric Nanogenerators - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue ACS Omega Année : 2022

Poly(vinylidene fluoride)-Stabilized Black γ-Phase CsPbI3Perovskite for High-Performance Piezoelectric Nanogenerators

Résumé

Halide perovskite materials have been recently recognized as promising materials for piezoelectric nanogenerators (PENGs) due to their potentially strong ferroelectricity and piezoelectricity. Here, we report a new method using a poly(vinylidene fluoride) (PVDF) polymer to achieve excellent long-term stable black γ-phase CsPbI3and explore the piezoelectric performance on a CsPbI3@PVDF composite film. The PVDF-stabilized black-phase CsPbI3perovskite composite film can be stable under ambient conditions for more than 60 days and over 24 h while heated at 80 °C. Piezoresponse force spectroscopy measurements revealed that the black CsPbI3/PVDF composite contains well-developed ferroelectric properties with a high piezoelectric charge coefficient (d33) of 28.4 pm/V. The black phase of the CsPbI3-based PVDF composite exhibited 2 times higher performance than the yellow phase of the CsPbI3-based composite. A layer-by-layer stacking method was adopted to tune the thickness of the composite film. A five-layer black-phase CsPbI3@PVDF composite PENG exhibited a voltage output of 26 V and a current density of 1.1 μA/cm2. The output power can reach a peak value of 25 μW. Moreover, the PENG can be utilized to charge capacitors through a bridge rectifier and display good durability without degradation for over 14 000 cyclic tests. These results reveal the feasibility of the all-inorganic perovskite for the design and development of high-performance piezoelectric nanogenerators. © 2022 American Chemical Society. All rights reserved.
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hal-03660966 , version 1 (19-02-2024)

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Paternité - Pas d'utilisation commerciale - Pas de modification

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W. Zhu, A.A. Khan, M.M. Rana, R. Gautheron-Bernard, N.R. Tanguy, et al.. Poly(vinylidene fluoride)-Stabilized Black γ-Phase CsPbI3Perovskite for High-Performance Piezoelectric Nanogenerators. ACS Omega, 2022, 7 (12), pp.10559-10567. ⟨10.1021/acsomega.2c00091⟩. ⟨hal-03660966⟩
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