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Article Dans Une Revue Green Chemistry Année : 2021

Oxidative esterification of alcohols by a single-side organically decorated Anderson-type chrome-based catalyst

Jingjing Wang
Feng Jiang
Chaofu Tao
  • Fonction : Auteur
Han Yu
  • Fonction : Auteur
Yongge Wei
  • Fonction : Auteur

Résumé

The exploration of non-noble metal systems in direct esterification of alcohols faces great challenges. Here, a new system using [N(C4H9)4]3[CrMo6O18(OH)3C(OCH2)3CH2OH}] as catalyst to realize the efficient transformation from alcohols to esters without organic ligands. A variety of alcohols are tolerated in this system. The chrome- based catalyst can be recycled several times and still keep the original configuration and catalytic activity. We also propose the reasonable catalytic mechanism and prove the potential for industrial applications.

Domaines

Catalyse

Dates et versions

hal-03692656 , version 1 (15-06-2022)

Identifiants

Citer

Jingjing Wang, Feng Jiang, Chaofu Tao, Han Yu, Laurent Ruhlmann, et al.. Oxidative esterification of alcohols by a single-side organically decorated Anderson-type chrome-based catalyst. Green Chemistry, 2021, 23 (7), pp.2652-2657. ⟨10.1039/D1GC00161B⟩. ⟨hal-03692656⟩
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