Intramolecular “Hydroiminiumation” of Alkenes: Application to the Synthesis of Conjugate Acids of Cyclic Alkyl Amino Carbenes (CAACs) - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Angewandte Chemie International Edition Année : 2007

Intramolecular “Hydroiminiumation” of Alkenes: Application to the Synthesis of Conjugate Acids of Cyclic Alkyl Amino Carbenes (CAACs)

Résumé

A rival for the hydroamination reaction: The intramolecular “hydroiminiumation” reaction features some distinct advantages over intramolecular hydroamination since the resulting prochiral iminium ions potentially allow the subsequent addition of a large range of nucleophiles to afford a new stereogenic center α to the nitrogen atom

Dates et versions

hal-03739644 , version 1 (28-07-2022)

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Rodolphe Jazzar, Rian D. Dewhurst, Jean-Baptiste Bourg, Bruno Donnadieu, Yves Canac, et al.. Intramolecular “Hydroiminiumation” of Alkenes: Application to the Synthesis of Conjugate Acids of Cyclic Alkyl Amino Carbenes (CAACs). Angewandte Chemie International Edition, 2007, 46 (16), pp.2899-2902. ⟨10.1002/anie.200605083⟩. ⟨hal-03739644⟩

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