Mono- and Diaminocarbenes from Chloroiminium and -amidinium Salts: Synthesis of Metal-Free Bis(dimethylamino)carbene - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Journal of the American Chemical Society Année : 2004

Mono- and Diaminocarbenes from Chloroiminium and -amidinium Salts: Synthesis of Metal-Free Bis(dimethylamino)carbene

Résumé

Bis(trimethylsilyl)mercury cleanly reacts at low temperature with chloroamidinium and -iminium chlorides, generating persistent metal-free cyclic and acyclic diaminocarbenes, as well as transient aryl-, chloro-, and hydrogenoaminocarbenes; with the latter, the corresponding olefin dimers were isolated, whereas with the former, no dimerization processes were observed.

Dates et versions

hal-03739745 , version 1 (28-07-2022)

Identifiants

Citer

Michael Otto, Salvador Conejero, Yves Canac, Vadim Romanenko, Valentyn Rudzevitch, et al.. Mono- and Diaminocarbenes from Chloroiminium and -amidinium Salts: Synthesis of Metal-Free Bis(dimethylamino)carbene. Journal of the American Chemical Society, 2004, 126 (4), pp.1016-1017. ⟨10.1021/ja0393325⟩. ⟨hal-03739745⟩

Collections

CNRS
3 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More