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Article Dans Une Revue Catalysts Année : 2022

Sorbent and Photocatalytic Potentials of Local Clays for the Removal of Organic Xenobiotic: Case of Crystal Violet

Sadou Dalhatou
Mouhamadou Sali
Samuel Tetteh
Hicham Zeghioud
Abdoulaye Kane
Atef El Jery
David Olubiyi Obada

Résumé

Natural materials are widely used in the field of environmental remediation and are appreciated for their surface physical and chemical properties. Clay constitutes a typical example. In this work, we report the evaluation of sorbent and photocatalytic potentials of local clay of two irrigated rice field waters in the degradation of crystal violet. The structural, textural and compositional properties of the local clay were investigated by Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD) and X-ray Fluorescence (XRF) analysis. The analysis results showed that these materials were composed mainly of quartz and kaolinite. The efficiency of these adsorbents (Y. Clay and L. Clay) to eliminate crystal violet dye from aqueous medium was examined at different initial concentrations, pH, contact time, adsorbent dose and the possible interference of inorganic salts from fertilizers. Kinetic studies showed that the adsorption process was well described by the pseudo-second order model and the equilibrium modelling results fitted adequately to the Freundlich model. The maximum amount of uptake capacity achieved at pH 2.0 was 18.40 (mg·g−1) and 20.40 (mg·g−1), respectively, for Y. Clay and L. Clay. The evaluation of the photocatalytic potential showed that the raw clay samples do not show photocatalytic activities during the 30 min of exposure to UV light. On the other hand, their photocatalytic potential is manifested when loaded with titanium dioxide (TiO2). Clays coupled with TiO2 under UV light showed an improvement in the degradation of the crystal violet dye by 15%. The synergistic effects between the high photocatalytic activity of TiO2 and the strong adsorption capacity of clays can be one promising technique for in situ remediation of contaminated soaked rice field.
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hal-03767354 , version 1 (14-09-2022)

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Sadou Dalhatou, Mouhamadou Sali, Samuel Tetteh, Abdoulaye Boubakari, Bouba Talami, et al.. Sorbent and Photocatalytic Potentials of Local Clays for the Removal of Organic Xenobiotic: Case of Crystal Violet. Catalysts, 2022, 12 (8), pp.899. ⟨10.3390/catal12080899⟩. ⟨hal-03767354⟩
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