Proof of Principle: Immobilisation of Robust Cu II 3 Tb III -Macrocycles on Small, Suitably Pre-functionalised Gold Nanoparticles - Archive ouverte HAL Access content directly
Journal Articles Chemistry - A European Journal Year : 2017

Proof of Principle: Immobilisation of Robust Cu II 3 Tb III -Macrocycles on Small, Suitably Pre-functionalised Gold Nanoparticles

Abstract

A highly stable and processable macrocyclic Single-Molecule Magnet (SMM) containing one Tb III and three Cu II ions in the core structure was covalently grafted onto gold nanoparticles pre-functionalised with carboxylate terminated tethers. The modified microemulsion method allowed production of small and monodisperse nanoparticles (about 3.5 nm in diameter) for the chemisorption of a huge amount of molecules, with retention of the SMM behavior in the final hybrid system.
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Dates and versions

hal-03989107 , version 1 (14-02-2023)

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Humphrey L C Feltham, Christophe Dumas, Matteo Mannini, Edwige Otero, Philippe Sainctavit, et al.. Proof of Principle: Immobilisation of Robust Cu II 3 Tb III -Macrocycles on Small, Suitably Pre-functionalised Gold Nanoparticles. Chemistry - A European Journal, 2017, 23 (11), pp.2517-2521. ⟨10.1002/chem.201604821⟩. ⟨hal-03989107⟩

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