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Toward phenanthridin-2-ylidene: electrophilicity versus acidity in planar-constrained C-aryl iminium salts

Xavier Cattoën , Didier Bourissou , Guy Bertrand
Tetrahedron Letters, 2006, 47 (4), pp.531-534. ⟨10.1016/j.tetlet.2005.11.052⟩
Journal articles hal-00180073v1

Mesoionic carbene-Breslow intermediates as super electron donors: Application to the metal-free arylacylation of alkenes

Wei Liu , Adam Vianna , Zengyu Zhang , Shiqing Huang , Linwei Huang et al.
Chem Catalysis, 2021, 1 (1), pp.196-206. ⟨10.1016/j.checat.2021.03.004⟩
Journal articles hal-03872959v1

1 H -1,2,3-Triazol-5-ylidenes: Readily Available Mesoionic Carbenes

Gregorio Guisado-Barrios , Michèle Soleilhavoup , Guy Bertrand
Accounts of Chemical Research, 2018, 51 (12), pp.3236-3244. ⟨10.1021/acs.accounts.8b00480⟩
Journal articles hal-02106394v1

Tandem copper hydride–Lewis pair catalysed reduction of carbon dioxide into formate with dihydrogen

Erik Romero , Tianxiang Zhao , Ryo Nakano , Xingbang Hu , Youting Wu et al.
Nature Catalysis, 2018, 1 (10), pp.743-747. ⟨10.1038/s41929-018-0140-3⟩
Journal articles hal-02106386v1
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Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes

Alex J Mantanona , Daniel R Tolentino , Kristine S Cay , Milan Gembicky , Rodolphe Jazzar et al.
Dalton Transactions, 2020, 49 (8), pp.2426-2430. ⟨10.1039/c9dt04624k⟩
Journal articles hal-03086591v1

Ionic-type reactivity of 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyls : regio- and stereoselective addition of hydracids

Guy Bertrand , D. Bourissou , Gad Fuks , Nathalie Saffon , Laurent Maron et al.
Journal of the American Chemical Society, 2009, 132, pp.13681-13689
Journal articles hal-00444590v1

Synthesis and ligand properties of a stable five-membered-ring vinylidenephosphorane

Matthew Asay , Antoine Baceiredo , Guy Bertrand , F.P. Cossio , Tsuyoshi Kato et al.
Angewandte Chemie International Edition, 2008, pp.7530-7533
Journal articles hal-00372227v1

1,3 -diborata- 2,4- diphosphoniocyclobutane- 1,3 - diyls communicate through a para- phenylene linker

Guy Bertrand , Jean-Baptiste Bourg , D. Bourissou , Gad Fuks , Amor Rodriguez et al.
Dalton Transactions, 2008, pp.4482-4487
Journal articles hal-00371327v1

Mechanism of the Exchange Reaction of Halodiazirines with Nucleophiles Revisited. Synthesis of Neutral, Mono-or Dicationic 4-16-Membered Phosphorus Heterocycles

Gilles Alcaraz , Valérie Piquet , Antoine Baceiredo , Françoise Dahan , Wolfgang W Schoeller et al.
Journal of the American Chemical Society, 1996
Journal articles hal-03435664v1

Comparative reactivity of different types of stable cyclic and acyclic mono- and diamino carbenes with simple organic substrates

David Martin , Yves Canac , Vincent Lavallo , Guy Bertrand
Journal of the American Chemical Society, 2014, 136 (13), pp.5023-5030. ⟨10.1021/ja412981x⟩
Journal articles hal-00992424v1

The serendipitous discovery of a readily available redox-bistable molecule derived from cyclic(alkyl)(amino)carbenes

Janell Mahoney , Vianney Regnier , Erik Romero , Florian Molton , Guy Royal et al.
Organic Chemistry Frontiers, 2018, 5 (13), pp.2073-2078
Journal articles hal-02048048v1

An unusual norcaradiene/tropylium rearrangement from a persistent amino-phosphonio-carbene

Joan Vignolle , D. Bourissou , Bruno Donnadieu , Guy Bertrand
Tetrahedron Letters, 2007, 48, pp.685-687
Journal articles hal-00197073v1

Transient Amino-Hydrazino-Carbenes: A Radical Pathway for Intramolecular 1,2-Migration Reactions

Xavier Cattoën , Heinz Gornitzka , Fook S. Tham , Karinne Miqueu , Didier Bourissou et al.
European Journal of Organic Chemistry, 2007, 2007 (6), pp.912-917. ⟨10.1002/ejoc.200600901⟩
Journal articles istex hal-00180055v1
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Cyclic (Alkyl)(amino)carbenes: Synthesis of Iminium Precursors and Structural Properties

François Vermersch , Luana Oliveira , Joseph Hunter , Michele Soleilhavoup , Rodolphe Jazzar et al.
Journal of Organic Chemistry, 2022, 87 (5), pp.3511-3518. ⟨10.1021/acs.joc.1c03075⟩
Journal articles hal-03716876v1
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What Are the Radical Intermediates in Oxidative N -Heterocyclic Carbene Organocatalysis?

Vianney Regnier , Erik Romero , Florian Molton , Rodolphe Jazzar , Guy Bertrand et al.
Journal of the American Chemical Society, 2019, 141 (2), pp.1109-1117. ⟨10.1021/jacs.8b11824⟩
Journal articles hal-02106385v1

Understanding the Activity and Enantioselectivity of Acetyl-Protected Aminoethyl Quinoline Ligands in Palladium-Catalyzed β-C(sp 3 )–H Bond Arylation Reactions

Erik Romero , Gang Chen , Milan Gembicky , Rodolphe Jazzar , Jin-Quan Yu et al.
Journal of the American Chemical Society, 2019, ⟨10.1021/jacs.9b06746⟩
Journal articles hal-02324460v1

A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand

David Martin , Vanessa M. Marx , Robert H. Grubbs , Guy Bertrand
Advanced Synthesis and Catalysis, 2016, 358 (6), pp.965 - 969. ⟨10.1002/adsc.201501140⟩
Journal articles hal-01644541v1

Rearrangement of biaryl monoaminocarbenes via concerted asynchronous insertion into aromatic C-H bonds

Matthew Asay , Guy Bertrand , D. Bourissou , Karinne Miqueu , Joan Vignolle et al.
Organic Letters, 2008, pp.4299-4302
Journal articles hal-00371286v1

Synthesis of extended polyphosphacumulenes

David Martin , Fook S. Tham , Antoine Baceiredo , Guy Bertrand
Chemistry - A European Journal, 2006, 12, pp.8444-8450
Journal articles hal-00145002v1

The Advantages of Cyclic Over Acyclic Carbenes To Access Isolable Capto-Dative C-Centered Radicals

Janell Mahoney , Rodolphe Jazzar , Guy Royal , David Martin , Guy Bertrand et al.
Chemistry - A European Journal, 2017, 23 (25), pp.6206 - 6212. ⟨10.1002/chem.201700144⟩
Journal articles hal-01649383v1

Synthesis of 2H-Azirine by [1+2]-Cycloaddition of a Phosphinocarbene with a Nitrile and its Ring-Expansion to 1,2 lambda 5-Azaphosphete

Gilles Alcaraz , Ulrich Wecker , Antoine Baceiredo , Franqoise Dahan , Guy Bertrand et al.
Angewandte Chemie International Edition, 1995
Journal articles hal-03435657v1

A stable P-Heterocyclic carbene

Antoine Baceiredo , Heinz Gornitzka , Wolfgang W. Schoeller , David Martin , Guy Bertrand et al.
Angewandte Chemie International Edition, 2005, pp.1700-1703
Journal articles hal-00357834v1

Air-Persistent Monomeric (Amino)(carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes

Janell Mahoney , David Martin , Fabrice Thomas , Curtis E. Moore , Arnold L. Rheingold et al.
Journal of the American Chemical Society, 2015, 137 (23), pp.7519 - 7525. ⟨10.1021/jacs.5b04414⟩
Journal articles hal-01650763v1
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Cyclic (Alkyl)(amino)carbene Ligands Enable Cu‐Catalyzed Markovnikov Protoboration and Protosilylation of Terminal Alkynes: A Versatile Portal to Functionalized Alkenes**

Yang Gao , Sima Yazdani , Aaron Kendrick , Glen Junor , Taeho Kang et al.
Angewandte Chemie International Edition, 2021, 60 (36), pp.19871-19878. ⟨10.1002/anie.202106107⟩
Journal articles hal-03349897v1

Modular Approach to Kekulé Diradicaloids Derived from Cyclic (Alkyl)(amino)carbenes

Max Hansmann , Mohand Melaimi , Dominik Munz , Guy Bertrand
Journal of the American Chemical Society, 2018, 140 (7), pp.2546-2554. ⟨10.1021/jacs.7b11183⟩
Journal articles hal-02106391v1

Organic Mixed Valence Compounds Derived from Cyclic (Alkyl)(amino)carbenes

Max Hansmann , Mohand Melaimi , Guy Bertrand
Journal of the American Chemical Society, 2018, 140 (6), pp.2206-2213. ⟨10.1021/jacs.7b11184⟩
Journal articles hal-02106392v1

Synthesis of a mixed phosphonium-sulfonium bisylide R3P=C=SR2

Tsuyoshi Kato , Guy Bertrand , Nathalie Saffon , Antoine Baceiredo , Sergio Pascual et al.
Angewandte Chemie International Edition, 2007, 46, pp.9078-9080
Journal articles hal-00266667v1

A stable (amino) (phosphino) carbene as bibentate ligand for palladium and nickel complexes : Synthesis, structure, and catalytic activity

Emmanuelle Teuma , Celine Lyon , Gerard Mignani , Antoine Baceiredo , Guy Bertrand et al.
Journal of Organometallic Chemistry, 2005, 690, pp.5541-5545
Journal articles hal-00361289v1

Evidence for Imidoylnitrene Intermediates in the Reaction of Bromophenyldiazirine with Phosphines: First Ring-Expansion Reaction of a Diazirine

Gilles Alcaraz , Antoine Baceiredo , Martin Nieger , Guy Bertrand
Journal of the American Chemical Society, 1994
Journal articles hal-03435616v1

X-ray Crystal Structure, ab Initio Calculations, and Reactivity of 1,3,2λ 5 -Diazaphosphetes: A New Type of 4-π-Electron 4-Membered Heterocycle

Gilles Alcaraz , Antoine Baceiredo , Martin Nieger , Wolfgang W Schoeller , Guy Bertrand et al.
Inorganic Chemistry, 1996
Journal articles hal-03435675v1