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Communication Dans Un Congrès Année : 2003

Micro-mechanical modelling of small and large strain behaviour of particulate nanocomposites

Résumé

This work presents experimental results and micro-mechanical modelling of the small and large strain behaviour of particulate nanocomposites consisting of a soft polymeric matrix filled with rigid submicronic (either PS or silica) inclusions. The small strain properties appeared to be governed by filler-filler interactions as soon as a percolating filler network is developed (> 20%). To account for these observations, a discrete simulation which takes into account the nature of contact between reinforcing particles has been developed. However, the large strain properties can be correctly modelled by means of homogenisation techniques, suggesting that the filler network is broken very soon. INTRODUCTION Nanocomposite materials consist of a nanometer-scale phase in combination with another phase acting as a matrix. Work about polymer nanocomposites has exploded over the last few years. Their properties are reported to be different from that of their micro-scale counterparts 1,2. These unusual properties may be a consequence of (i) the extremely high interfacial specific area which can reach 100-1000 m 2 /g and (ii) the very short average distance between reinforcing fillers (about 10-8 m), down to a value comparable with the macromolecule coils. This can favor the short-distance filler-filler interactions leading, above a critical volume, to the formation of a network (percolation). Though significant progress has been made in developing nanocomposites with different polymer matrices, a general understanding has yet to emerge. A major challenge to further development of nanocomposites is the development of specific micro-mechanical models.
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hal-00116378 , version 1 (09-04-2024)

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  • HAL Id : hal-00116378 , version 1

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Emmanuelle Chabert, Michel Bornert, Jean-Yves Cavaillé, Rémy Dendievel, Catherine Gauthier, et al.. Micro-mechanical modelling of small and large strain behaviour of particulate nanocomposites. ICTAM XXI : XXI International Congress of Theoretical and Applied Mechanics, 2003, Varsovie, Poland. pp.75-78. ⟨hal-00116378⟩
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