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Article Dans Une Revue Heteroatom Chemistry Année : 2001

Destruction of chemical warfare agents VX and soman by [alpha]-nucleophiles as oxidizing agents

Résumé

Reactions of O-ethyl S-(2-diisopropyl-amino)ethyl methylphosphonothiolate, VX 1, were investigated with five oxidizing agents. In all the cases, the formation of the VX N-oxide 7 was observed prior to the subsequent oxidation and hydrolysis into the nontoxic O-ethyl methylphosphonate 2. Magnesium monoperoxyphthalate (MMPP) is probably one of the most active reagents to achieve the complete detoxification of VX 1. The decontamination using MMPP was also extended with success to soman 13, a G-type agent.

Domaines

Chimie organique

Dates et versions

hal-00167978 , version 1 (23-08-2007)

Identifiants

Citer

Thierry Cassagne, Henri-Jean Cristau, Gérard Delmas, Michel Desgranges, Claude Lion, et al.. Destruction of chemical warfare agents VX and soman by [alpha]-nucleophiles as oxidizing agents. Heteroatom Chemistry, 2001, 12 (6), pp.485-490. ⟨10.1002/hc.1074⟩. ⟨hal-00167978⟩
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