A three-coordinate Fe(ii) center within a [3Fe-(μ3-S)] cluster that provides an accessible coordination site. - BIG - Chimie et Biologie des Métaux (CBM) Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2016

A three-coordinate Fe(ii) center within a [3Fe-(μ3-S)] cluster that provides an accessible coordination site.

Résumé

A μ3-sulfide bridged triiron cluster(ii,ii,iii) supported by a cyclophane ligand undergoes metal-based reduction to yield an all-ferrous species. The latter complex incorporates a three-coordinate iron center that provides an accessible coordination site to a solvent molecule.

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Chimie
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Dates et versions

hal-01352745 , version 1 (09-08-2016)

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Yousoon Lee, Khalil A. Abboud, Ricardo Garcia-Serres, Leslie J. Murray. A three-coordinate Fe(ii) center within a [3Fe-(μ3-S)] cluster that provides an accessible coordination site.. Chemical Communications, 2016, 52 (59), pp.9295-9298. ⟨10.1039/c6cc04671a⟩. ⟨hal-01352745⟩
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