First Structurally Characterized Tricyanomanganate(III) and its Magnetic {MnIII 2MII2} Complexes (MII = Mn, Ni) - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Inorganic Chemistry Année : 2010

First Structurally Characterized Tricyanomanganate(III) and its Magnetic {MnIII 2MII2} Complexes (MII = Mn, Ni)

Résumé

Treatment of tris(3-cyano2,4 pentanedionato)manganese(III) with KTp*, followed by [NEt4]CN affords [NEt4][(Tp*)MnIII(CN)3](1); subsequent treatment of 1 with divalent triflates (OTf) and 2,20- bipyridine (bpy) affords {MnIII 2MII2} complexes (MII = Mn, 2; Ni, 3). Magnetic measurements show that 1-3 exhibit ST = 1, 3, and 4 spin ground states, respectively.

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Dates et versions

hal-00504851 , version 1 (21-07-2010)

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Minao Tang, Dongfeng Li, Uma Prasad Mallik, Jeffrey R. Withers, Shari Brauer, et al.. First Structurally Characterized Tricyanomanganate(III) and its Magnetic {MnIII 2MII2} Complexes (MII = Mn, Ni). Inorganic Chemistry, 2010, 49 (11), pp. 4753-4755. ⟨10.1021/ic1006605⟩. ⟨hal-00504851⟩

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