New class of β-aminoalcohol ligands derived from isosorbide and isomannide: application in hydrogen transfer reduction of prochirales ketones - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Tetrahedron Année : 2010

New class of β-aminoalcohol ligands derived from isosorbide and isomannide: application in hydrogen transfer reduction of prochirales ketones

Résumé

Starting from isosorbide and isomannide, two by-products from the starch industry, a family of chiral functionalized β-aminoalcohols presenting a THF ring has been synthesized as potential ligands for hydrogen transfer reduction of prochiral ketones. Under optimal conditions, more than 70% ee with an excellent conversion were obtained for the HTR of the acetophenone.

Dates et versions

hal-00527862 , version 1 (20-10-2010)

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Citer

Tin Thanh Le, Stéphane Guillarme, Christine Saluzzo. New class of β-aminoalcohol ligands derived from isosorbide and isomannide: application in hydrogen transfer reduction of prochirales ketones. Tetrahedron, 2010, 66 (46), pp.8893-8898. ⟨10.1016/j.tet.2010.09.060⟩. ⟨hal-00527862⟩
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