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Article Dans Une Revue Journal of Organic Chemistry Année : 2012

Stereoselective and Catalytic Access to β-Enaminones: An Entry to Pyrimidines

Résumé

We describe herein a highly stereoselective access to Cbz-protected β-enaminones 2 based on the NaOH catalyzed rearrangement of propargylic hydroxylamines 1. The synthetic potential of these β-enaminones is illustrated in an original synthesis of pyrimidines.
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Dates et versions

hal-00739802 , version 1 (09-10-2012)

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Eric Gayon, Monika Szymczyk, Hélène Gérard, Emmanuel Vrancken, Jean-Marc Campagne. Stereoselective and Catalytic Access to β-Enaminones: An Entry to Pyrimidines. Journal of Organic Chemistry, 2012, ⟨10.1021/jo301675g⟩. ⟨hal-00739802⟩
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