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Article Dans Une Revue Journal of the American Chemical Society Année : 2014

Thermochromic and Photoresponsive Cyanometalate Fe/Co Squares: Toward Control of the Electron Transfer Temperature

Résumé

Two structurally related and photoresponsive cyanide-bridged Fe/Co square complexes, {Fe2Co2}, are reported: {[(TpMe)Fe(CN)3]2[Co(bpy)2]2[(TpMe)Fe- (CN)3]2}·12H2O (2) and {[(TpMe)Fe(CN)3]2[Co-(bpy)2]2[BPh4]2}·6MeCN (3), where TpMe and bpy are hydridotris(3-methylpyrazol-1-yl)borate and 2,2′-bipyridine, respectively.....

Domaines

Matériaux
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Dates et versions

hal-01092286 , version 1 (08-12-2014)

Identifiants

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Yuan-Zhu Zhang, Ferko Philip, Diana Siretanu, Rodica Ababei, Nigam P. Rath, et al.. Thermochromic and Photoresponsive Cyanometalate Fe/Co Squares: Toward Control of the Electron Transfer Temperature. Journal of the American Chemical Society, 2014, 136, pp. 16854-16864. ⟨10.1021/ja508280n⟩. ⟨hal-01092286⟩
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